http://en.wikipedia.org/wiki/Polaris_(poker_bot)
Hands in limit poker nearly always have a mathematically correct way to play; if a program executes the correct play every time and isn't figured out as a bot the program stands a pretty good chance of being profitable.
Most human players don't have the advantage of being able to memorize the correct action for every scenario, a well written bot has an absolute advantage with regards to the math involved.
Additionally, a poker bot remembers every hand it's ever played, as well as every hand it's ever seen played - there has been poker software available for many years that will analyze other player's play for weaknesses which can be trivially exploited. I would assume diligent poker bot creators know about this type of thing and are taking advantage of that as well.
I should've clarified no limit. This article is presumably talking about no limit - since that is by far the predominant game.
With all due respect, you have a poor understanding of poker if you really think there is a way to "memorize the correct action for every scenario". Poker is about interaction, spotaneity, 'feel', instinct. Mastering those things is where to get a real edge, not math - particularly in no limit. Hence my comment.
That being said, I'm fairly certain the article was not talking about no-limit. The vast majority of poker bots play limit, where there is a clear advantage from playing the mathematically correct way.
The idea that you can play winning poker with "spontaneity" and "feel" is exactly how these bots make money. I'm not going to waste my time trying to explain it to you. If you really care, spend more than 30 seconds reading up about the mechanics of limit poker.
I would suggest starting here, since it has a reasonably compact rundown of the math behind the game:
http://www.amazon.com/Theory-Poker-Professional-Player-Teach...
An objection that could be raised is that psychological factors carry more weight in no limit, especially short term psychology (recognizing when a player is on tilt), but I see no reason why a sophisticated program couldn't integrate these factors better than a human. Psychology in online poker is really just pattern analysis.
Poker is a game of incomplete information. The more information you possess, the better your odds are of making the right decision.
So, in the instance of 2 poker bots colluding on a table (the 4 suits are (c)lubs (d)iamonds (s)pades (h)earts):
Bot 1 has Ac5h and discards pre-flop (no money spent)
Bot 2 has KcQc and calls.
Player 3 calls
Player 4 calls
All other players discard
The flop comes up: 5c 10c 9c
At this point, Bot 2 has an excellent hand (a King-high flush), but it doesn't have the best possible hand; it's vulnerable to a higher flush due to the Ace. However, the because bot 1 & 2 have colluded, it knows with 100% certainty that it has an unbeatable hand and can play accordingly.This is a pretty weak example, but it's the easiest I could think of without assuming any knowledge of poker. Having knowledge of cards that have been in play significantly increases a player's ability to make decisions in a way that give that player an unfair advantage.
While your example is a good one, the bot actually doesn't have an unbeatable hand. Another player could have trips or 4/5 of a straight flush and hit a better hand (quads or a straight flush) on the turn/river. Or the board could pair twice and give someone a full house. Unlikely in any case, but not out of the realm of possibilities by any means.
but seriously, he means if the board is like: 2c 3c 7c Tc 4h, (not that he'd get much value from the guy with the lone Jc, though)
think of how easy squeezing is with two colluding bots.