"Shopping cart abandonment" is a specifically targeted "thing", and it's not unusual to get emails "reminding" me that I "forgot" that last crucial step of actually transacting.
Edit: It can also work the other way though - I've decided I'll purchase, see a coupon code box and think I might as well check (when I wouldn't have thought to otherwise), and ended up paying half the price (it was a monthly service though, and it made me less likely to cancel it when I wasn't using it as much, so they probably won in the end).
Anecdotally, there's been cases in the past where I see a product as valuable but overpriced, and a coupon makes the difference between a sale and a pass. I will go to the checkout screen with the product to try some coupons and see if they work, not having yet made the decision to proceed with the purchase.