There are iOS ad blockers on the Apple App Store, and extensions for MacOS Safari. I'm not sure how much more authorized it can get than that unless you want Tim Cook to hold your hand through the process.
In my opinion, the most important branch the Web could take right now is going from transparent content to opaque content. Now I can filter, transform, organize and augment content accessed through my browser, and even remix it, all enabled by the inherent organizing of the technology, which suggests to the larger society more can be done. It's an open question though, and that technology could be changed to restrict what can be done with content.
If Google wanted to include their own ad blocker with Chrome they could - it is highly unlikely that they would want to.
Still, it's clear Chrome could offer an adblocker if they wanted to.
[1] https://support.mozilla.org/en-US/kb/tracking-protection
A good ad blocker for Safari (on Mac or iOS) just uses the Content Blockers system, and provides essentially a JSON blob with a bunch of rules in it to Webkit, which will then take the requested actions (mostly block, sometimes hide elements, sometimes force a URL to https) internally - the Ad Blocker "app" never knows what sites you're visiting and is never involved in actual blocking.
I have (personally) never had the desire to write/run a userscript on iOS. If my device being a “smart tv” lets me focus more on other areas of my life (i.e. projects, hobbies, and career) rather than fiddling with my tools, then that’s a trade off I’m more than happy to make.
I suspect many other people share this point of view.