Having worked for and still working part-time for a major, as in top 5, vc firm, investors will definitely look for you on LinkedIn early on to ensure that you're a legit person with a good job history and a network.
This is even more important, when they are hiring for themselves.
There are so many grifters in tech, that investors and people hiring for leadership positions in startups feel the need to be able to draw a connection between your network and theirs.
Moreover, if investors are interested in your venture, they'll want you to create a profile and assembles a network. It's part of having visibility for your venture and a certain amount of legitimacy in the community. A company is people, and their leaders need an online presence outside of Github and fora.
I'm sure people will jump in with all kinds of anecdotal counter-examples, but this is what I've seen in a few years working for Sand Hill.
Could you explain why? I don’t see an obvious reason to avoid ex-Facebook employees
To me it would indicate the possibility that the person might not want to understand the wider implications of their work, might understand those implications but not care about them so long as they are personally or socially enriched, or might just agree with the duplicitous nature of the company. There are of course circumstances to account for, and everyone's reasons are different - but the above rationalizations would raise red flags for me - especially in my industry where thinking about wider implications of our work is absolutely critical.
Similarly, I'll be far less likely to hire one who has Facebook on their resume.