I just asked her to check her Facebook and she doesn't see any car ads. I checked too but didn't see any ads for cars or that brand, but I don't have the Facebook app on my phone (she does) and our Facebook profiles aren't strongly linked (i.e. she's not listed as my "wife", we just friend each other). She uses her phone for navigation while driving, so it was in a position to clearly hear us.
I haven't done any research on that car brand, but I suspect that once I do a Google search, then the ads will start flooding in.
So maybe this is confirmation bias in the other direction, but I don't see any evidence that Amazon Alexa, Facebook, or Google Assistant are spying on us. Though it could just mean that this particular carmaker doesn't purchase ads based on keyword spying
Try doing different things. I don’t think name brand vendors do pervasive audio surveillance. I do think they broaden the scope of your intents. Use GBoard dictation or similar tools to write. Write stuff down in different contexts. Use apps in different ways.
Amazon and Facebook share in near real time. Anything you do in a consumer Amazon property is feeding context to FB.
You are just not noticing these ads until it is something you have called out. You would never have given a second thought to this totally random item otherwise.
I have tried the same test as you multiple times just for kicks and have never found it to be confirmed.