And during rush hour, the highways are a lot more full, and often capacity (number of lanes) is increased to compensate. If people didn't typically commute at the same time, then busses, trains, and car transport would all benefit from a reduction in required peak capacity. This is not in any way specific to cars.
> If people didn't typically commute at the same time...
Absolutely! That would be ideal.
To increase the capacity of trains and busses, you need more trains/busses, larger trains/busses, more train/bus operators, more electricity/gas usage, more storage, more maintenance, and so on. And those same huge trains and busses also become near-empty late at night.
Yes, the baseline efficiency of a train or bus is potentially better, making all the standard tradeoffs. But everyone commuting at the same time causes similar problems with both. I'm not arguing against public transit, here, I'm arguing against the claim upthread that "This is a problem of a car centric society", which is orthogonal to a staggered commute.
(Sure, there’s places where even that isn’t enough and the public transport pipe is congested. We’ve all seen those videos of trains in some places in asia, for example)