Are there situations in which it is easier if the admin can just reset it, sure. Is that a good idea, no.
I have run into all three of these scenarios:
1) A login for an administrator area on a server has a different login/password than the main area, and the browser always fills in the main login/password, even though I ask it not to. autocomplete=off would fix this.
2) A new user and edit user screens exist in web apps that are driven by users sign-ups. Sometimes these things need to be coordinated with other systems in a corporation and users do not always have their own email (I know this is a shock for you, but it is very common). autocomplete=off would fix this.
3) Using a remote admin tool to setup a datasource on a server, the username and password fields refer to database credentials, not a person. Yet Chrome keeps filling in my info. autocomplete=off would fix this.
If you have a simple web app that has an administrator mode for editing accounts, you should be able to turn off autocomplete so your password doesn't automatically get filled in for users that you edit.
It's that simple.