I once had an auditor tell me that they are more suspicious of those who do not minimize taxes as they were those who fail to report income that the IRS is aware of but unreported on the return. Those who do not claim legitimate deductions are looked at as hiding something big per one examiner. She also stated that IRS examiners know all the "tips" for minimizing tax due and they certainly utilize every one applicable to their individual circumstances.
Oh and just as an aside, if you want to help the country beyond paying the minimum taxes that you legally owe, at any time a person can mail a check to the US Treasury with a letter that you would like said payment to be applied to deficit reduction.
Arbitrary rules set by states is not a moral barometer.