This isn't really true. Saccharomyces cerevisiae can't generally ferment starch directly, but various forms of Brettanomyces can. Wild yeast and bacteria that can ferment starch are pretty common -- a turbid mash (which leaves a bunch of starches in the wort) is still used before putting the wort into a cool ship to be inoculated with wild yeast and then fermented in barrels.
Granted, a true wild sour usually takes a few months to a few years to ferment out all the starches and develop the flavors that are so interesting, but "Yeast can't ferment starch directly" is an oversimplification.
For fun some years ago I made some moonshine using cornmeal and brown sugar. Built my own still too, fun stuff. Just gotta make sure everything is lead free and discard heads and tails.
I used a valved reflux still and kept temps within a couple degrees of ideal. Ran the result through carbon filters at the end. Couldn't tell the difference between my stuff and everclear