Here in Japan the majority of the highway system has been privatized and they all have tolls, and it seems to work just fine. Driving solo between two cities 4 hours away is often more expensive in tolls alone than taking the bullet train.
Far more efficient than toll roads, where you have to build toll infrastructure, hire employees, do enforcement and create traffic jams at every toll booth. RFID toll trackers are not enough in preventing the traffic jams. On top of that, you don't have to build anything to implement it today to create a usage tax for roads, since smog check equipment already checks your mileage. It also applies to all roads instead of a select few roads. To determine the distribution of where the tax money should go, you use the passive traffic tracker systems we have almost everywhere.