Note that the above is historical. GNOME selected GTK long ago and has somewhat strong armed GTK development away from GNOME. I don't follow either project closely enough to suggest how much.
https://git.gnome.org/browse/gimp/commit/?id=52ad5bb2a11e39f...
The default situation was that the toolbox grabbed the focus when clicked. That meant various actions, eg. "Show/hide docks", didn't work if the last thing you clicked was the toolbox. That's an annoyance created by "accepting the defaults", that's thankfully now been fixed in light of real-world usability issues.
Some aspects of Photoshop's user interface are patented, but it's much safer and wiser to LOOK at them and be aware of them and read the patents, so you're consciously aware of what not to do accidentally, and able to work around them.
I'm not sure the GIMP's UI choices can generally be described as "innovating". I think they're generally just the obvious GTK+ default options, implemented without much testing or tweaking.