Is there any evidence that this is actually due to their capability? I would say it's far more likely it's their environment. IE, people are constantly talking to young kids. They simplify what they say to make themselves understood. And children have a huge incentive to learn to communicate - to get what they want from parents, or just understand the world around them. The same isn't true for a grown adult trying to learn a second language, in isolation, that they don't really need in their day to day lives.
Disclaimer: this is pure conjecture.
I'm also aware of a few other age/skill type relations.
Musical ability frequently manifests early -- by age 4-5 in numerous historical cases.
Talents requiring physical coordination -- ballet and gymnastics -- around age 9-10 by Russian tradition.
Maths and scientific curiosity perhaps early adolescence.
Complex logic and activities requiring a fully developed inhibitory function (avoiding reflex and rash actions) possibly early 20s.
I'm suspecting other forms of more synthetic (as in: assembling from parts) logic might not develop fully until the 30s or 40s. Other skills might similarly not develop until later.
Montessori schools are said to be better on this score, though I haven't looked into them.
Neal Stephenson's Cryptonomicon, The Baroque Cycle, and Anathem, for example, are all explorations of ideas. The first two of business, banking, and money, in contemporary and historical times, respectively. The latter covers a great deal of historical thought.
Better authors of topics often incorporate humour in their writing -- someting the past few generations of academic literature would do well to consider. OTOH, it's a cure for insomnia.
1. Young children seem to have the biggest capability in learning languages.
2. There's the John Stuart Mill example -- homeschooled by his father in the classics and philosophy. Interesting biography (Wikipedia has a fair account).
3. There are children who are naturally skilled in art, storytelling, maths, sciences, music, etc. An opportunity to work to those strengths might be useful.
I've also noticed that a short period of instruction at the appropriate time often seems disproportionately effective.