Extending your second paragraph, when people interact with the IT desk, they're trying to go from a bad state up to their base state. When people interact with a library desk, they're trying to go from a base state up to anything above that.
Just speculating here, but I think it has to do with how a lot of people seem to look down on IT, and tend to blame them for their problems. With doctors, the people tend to look up to them, and don't blame them for their illnesses[0].
> when they called
I'm pretty sure this makes an enormous difference as well, btw, compared to face-to-face communication.
So we got three examples of service work, where the interaction with the customer completely shapes the experience for everyone involved.
[0] ignoring malpractice cases and such, but that's after treatment, not before.
I can't see the same being quite as true for librarians as people aren't starting from a state where something that should be working isn't.