VoIP, FaceTime, Skype and other IP-only technologies can use much better audio codecs, going all the way up to CD quality audio (44kHz, 16bit). This makes a huge difference when there is background noise and clipping and less than optimal transmission conditions.
(Source: I used to work for an IVR company.)
But... landline telephones have always mangled human speech. They're awful.
Thats not to say there arent legacy towers out there on POTS, but all new towers are on Ethernet via fiber as far as I can tell.
Also see https://en.wikipedia.org/wiki/Public_switched_telephone_netw... regarding the 64kbit/s limitation.
In a previous job most of my team worked out of Bulgaria, and I could hear them better over Skype on my iPhone than I could hear my wife on a regular phone call. Headphones helped the sound quality even more, but it really wasn't necessary.