50% employees are baristas.
35% are shift supervisors
15% assistant store manager or higher in the hierarchy
Which means the odds are overwhelming that every employee you interact with in a normal Starbucks doesn't have a college degree. So why this view that college grads are flocking to Starbucks because they can't find jobs.
In fact, Starbucks has started the free college option to make sure that even non-degreed people will find Starbucks attractive enough to apply. [2]
[1] http://www.bloomberg.com/bw/articles/2014-10-07/starbucks-is...
[2] https://news.starbucks.com/news/starbucks-offers-full-tuitio...
I avoided singling out the larger corporations at the end of my comment (Starbucks, McDonalds, Dunkin Donuts) as I don't have any friends who will be working service jobs for these chains.
I graduated undergrad a couple of months ago, and I do have a fair amount of friends who gave up looking for work in the finance/startup field full time and are now working at trendy restaurants/bars in the SF NY area to make ends meet while searching on the side. Anecdotal evidence, but that's what I've seen.
I would also add that despite quoting juicy statistic from your article, you don't seem to have read it accurately - there's no about how many baristas have degrees. The only comment is that 25% of all employees have degrees. I don't have the data tell what the chance is that the average Starbucks barista has a college degree but I'd claim neither do you if you're just going by that article.
Starbucks is hiring, but a lot of the workforce that is unemployed is overqualified with bachelor degrees that they thought would guarantee them a safe job on a nice career track. Upon graduation, they are finding that there is a shrinking pool of jobs for them, and that they'll either have to retrain (do a masters or do a crash coding course) or take a job well below what they expected with their degree.
Most of these people will have to rely on connections or networking to get a decent job, and the unlucky ones will join the services industry and work as a barista or a waiter, providing the infrastructure for the tech gold rush.