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Re:The Evidence Points to a Better Way to Fight Insomnia by beagle3 on Wednesday June 10, 2015 @09:38AM (#9692036)
I don't think there's a peer review study, but in the quantified self community, it is common knowledge that you should take it early (5am - 10am) or you will harm your sleep instead of helping it.

It is a http://en.wikipedia.org/wiki/Zeitgeber , and you might want to read http://www.gwern.net/Zeo

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