I really loved his note about Dima who asked everyone to swap chairs around. The group had one more person than there were chairs, yet with each shuffling he was bewildered to find they were still short one chair. The child wasn't dumb, and in fact is occasionally clever, but this isn't the sort of problem to be curious at - it's baffling. (Though that's not to say Dima didn't reflect on it at a later date - I'm only halfway through.) The fact Dima didn't quite understand the problem is the part of the interesting point being made; something seems off, but Dima didn't understand to dig into it and figure out right then why this situation felt wrong, at least not yet. Indeed, shortly after on page 28 he notes that this sort of misunderstanding could happen to an old person, too, despite their longer lives and observations.
I think part of the lesson here is that the lessons don't even really stimulate curiosity. Rather, it gives the children more information, more opportunities to have that special serendipitous 'aha!' moment. To your point, it's more akin to bringing the child to a curious place and letting them do their natural thing, rather than foisting stimulation onto them.
Kids are curious out of the box, but if you gently guide them, they are capable of asking amazing questions and understanding things that will blow you away. My kindergarten nephew and my two year old inspire me this way.