Due Process does not require a courtroom. That does not mean that "any established process" will suffice. The amount of process due depends on the context. The open-endedness of the concept is embedded in the phrase itself: the word "due" means "warranted" or "appropriate."
I don't think there's a Supreme Court case specifically involving police officers, but the general idea that public employees have protections against suspension is well-established: http://www.huizenga.nova.edu/course-materials/6240/cases/Con....
For example, there are seminal court cases that lawyers know in which 1) a person has their welfare benefits revoked, 2) a person has their disability benefits revoked, 3) a tenured public university professor is fired, and by knowing those cases, you gain an understanding how most courts would likely view the suspension of pay of an officer with no notice or hearing of any kind. Different facts will obviously change the results, and different courts may come to different conclusions, but the current test and existing case law is not impossibly vague or unworkable.
http://www.thewire.com/national/2012/03/holder-due-process-d...
>"Three factors are relevant in determining what process is constitutionally due: (1) the private interest that will be affected by the official action; (2) the risk of an erroneous deprivation of such interest through the procedures used, and the probable value, if any, of additional or substitute procedural safeguards; and (3) the Government's interest."
These are impossibly vague and open-ended. That's actually my only point. What I'd like to see is a case where the Supreme Court said that a policeman could not be suspended without pay, decided on constitutional grounds.