If none of those work, I often pass on spam reports that people tweet to me (or when they do a blog post and tweet me that link). You can also tweet to @googlewmc (for Google Webmaster Central). Or if you add an email address on your HN profile, I'll drop you a note.
I have tried the first link several times with no luck. I've heard that it's a myth that it actually gets checked but seems that may be wrong :)
I will try all the other avenues mentioned and worst case will fly to Seattle to report this site in person. Site that is blatantly spamming is plaintube and is ranking for an insane amount of adult terms. I'll try to get my point across via the methods you described. It would be wrong of me to hijack this thread to get my point across anymore. Thanks for your time.
I'm surprised that such tactics work in 2014, and am just as surprised that I got your attention. Hacker news is a powerful place!
I have tried reporting a website that buys 100% of its links (I used to work for them and have tons of proof) and is being rewarded with 2.5-3mil hits a day from google and yet no one seems to care! Is there a way to get my point across or do I have to write a blog post that gets picked up by HN to get any action taken?