If it helps, don't think of the words as words, but instead as random numbers. It just so happens that these random numbers are presented in a form that's easier to remember. And 4 random numbers between 0 and 2048 cannot be easily guessed.
The expected entropy is derived from "correct horse battery staple", including the spaces, using NIST SP 800-63.
So yeah maybe it is implicit in the comic, but the math is backed by a specific set of assumption on how the words were selected. Or I could be wrong, I haven't verified it personally.
First character is 4 bits: c = 4
The next 7 chars are 2 bits/each: "orrect " = 14
Characters 9-20 are 1.5 bit/each: "horse batter" = 18
Charactes 21-n are 1 bit/each: "y staple" = 8
No bonus for including both upper and non-alpha chars.
No bonus for passwords of length less than 20 chars, not containing dictionary words, because the password is longer than 20 characters.
Total entropy: 4 + 14 + 18 + 8 = 44 bits of entropy.
The NIST entropy estimation is based off of characters that aren't chosen at random (I think?) and it is a heuristic.
For the approach I think Randall intended to describe they aren't really words, just glyphs chosen randomly from a set of glyphs. That these glyphs are easy to memorize and drop right into existing password interfaces is orthogonal.
And pass phrases will tend away from words like perspicacious.
Maybe the author just didn't think of Kolmogorov complexity and thought it was a good idea.
The other message is: stop posting XKCD #936 for the bazillionth time, you assholes.
This style of concocting passphrases (chain dictionary words together) as a whole has a low Kolmogorov complexity, and can easily be imported by attackers through wordlist mangling or using some advanced software features, such as Hashcat's combinator attack.
Finally, humans are fallible. They'll always go for certain predictable combinations, and certain permutations will be more widespread among those.
If an attacker has any suspicion you're using the XKCD algorithm literally, it's trivial for them to make a move.