NY, the most subway-centric city, has the longest commutes in the US. LA, "the most car centric city" (probably not literally true) tends to have amongst the shortest.
Decommission those NYC subways and replace with private shuttles and busses. Bet you'll see dramatic drops in commute times for NYC. And it'll save incredible, incredible amounts of money.
Edit: Citation: http://www.nydailynews.com/new-york/new-yorkers-havelongest-...
The NYC subway system is also a red herring. The subway primarily serves Manhattan, The Bronx, and Brooklyn. Of those people who commute into Manhattan from another borough, a plurality come from Queens, half of which has no subway coverage at all; that's for people inside NYC proper and obviously excludes NJ, Westchester, and Long Island commuters.
NY has much, much higher population density than LA, which probably both explains why it was more subway-centric and why commutes are longer.
The fact that LA metro has such short commutes - despite being one of the largest and most car dependent big cities in the world - suggests that highways and private cars do, in fact, scale very well.
It'll never happen, as it's opposed by (1) Taxi operators, (2) Mass transit operators & unions, AND (3) Do-gooders who don't want private business to succeed where public service has failed.
I think that one reason for that is that, for reliable connections, one needs a multiple-connected graph. Users must be able to 'go around' any disturbance that arises.