Not that I believe that there's a secret button.
Interestingly enough, most classified information doesn't get leaked the same way that Snowden leaked his documents. It's mostly due to carelessness. The best example of this is deployment schedules. One of my coworkers was scheduled to go on a Marine Expeditionary Unit (ship that goes around the Pacific just in case something happens). The date of departure was classified. Someone told his wife, who told all of her friends on Facebook. Oops.
Trying to keep a "detain"-button secret, having it manned by thousands of people that only have a high school diploma OR a year of work experience in security/aviation/screening, doesn't sound easy (those are by the way the education requirements for a TSO according to usajobs.gov). Since a leak could stem from a minor overstep of their contract (ohh, I told a buddy about it, big deal right?), and there are frequent policy violations by agents, it does look grim for the existence of such a button.
I heard of them kicking the machines to make them go off though, so there's a "button", and it's public knowledge that they will use it if they want a pat down.
The only way to keep a secret for long periods is that few know about it.