The main thing is that while Persona talks about email verification, the protocol doesn't require that email handling exists. Just that a server vouches for the existence of a user@host, so using MX records wouldn't be 'correct' even if it would be a useful heuristic for google apps domains.
There has been talk of using SRV records, but it looks like the .well-known/browserid file will be the recommended way to do things.
[1] https://developer.mozilla.org/en-US/docs/Mozilla/Persona/.we...
Using the mx record would be bad, because, if you are doing it yourself, then your email server would have to also have a persona authenticating server, it would be hard to use your own persona authenticating server and have a third party take care of email, etc.
That said... here is one of the building blocks https://github.com/mozilla/browserid/issues/2932
Get involved and implement this as a NodeJS module.
Looking for that "aspmx.l.google.com" entry in the MX record would let them know, with a high degree of certainty, that Google is the login authority for that particular email address.
Is there something I'm missing?