Here are three I can remember (there might be others I don't know):
Andrew Schulte as chief of Staff: http://hothardware.com/News/Yahoo-Chief-Marissa-Mayer-Poache...
Dylan Casey senior director in the platform organization: http://searchengineland.com/former-google-product-manager-go...
de Castro as chief operating officer: http://online.wsj.com/article/SB1000087239639044435400457805...
Also I replied else where how the Yahoo working environment changed since Mayer joined:
http://www.quora.com/Yahoo/Is-it-true-that-Yahoo-is-better-t...
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At the end of day we will just have to wait and see how Mayer's strategy pans out. At least from what I can see she is taking things to the right direction.
Culture is pushed from the top. If you're changing the culture at the top then bringing new people in lower down might speed up the change and solidify it but in of itself it won't change anything if nothing is changing at the top.
But if they see execs who really get it, they may endure a line or middle manager who doesn't get it, knowing that it's just a matter of time.
Just think about it in terms of code - you write some code as a standalone demo - to bring it into your main application, you end up having to integrate into most of the existing framework, and that influences the original demo code - often for the better, but that depends on the quality of the existing code base - and how well it was architected (by the code equivalent of the execs).
Very few companies do acquisitions where they carefully protect the acquired company. The assumption is that the buying companies culture is better! One company that does do this quite well is Conde Naste. (Wired, Reddit, etc. all have quite separate identities, and from the outside appear to have autonomy.)
When you start to see an exodus of long term Yahoo! execs, then she's probably doing something right. Whether Wall Street would reward her for that, is a totally different question!!!