If you start a company, however, your returns vary extensively. If you're smart and dedicated after five years you might come out broke - or even in debt. Or you'll come out being barely able to make the rent. Or you'll be a millionaire or billionaire. As an entrepreneur, your risk five year returns would be somewhere between -$100,000 to $10,000,000+, with the expectation I would guess quite a bit lower than the Googler's.
That's not to say that either is the right choice - mathematically, the big corporation choice will make you more money in the expectation and probably take less of your time. But you know, life's not about optimizing the integral of income over your career.
That's why I suggested picking a big corporation with more of a reputation for "doing what you're told", like IBM, Cisco, or even Apple. Google in a couple years might be there, but right now you cannot get to the higher engineering levels without sticking your neck out on an initiative that may be controversial at first.
(It's also true that the risk/reward curve is flattened a bit at Google than at a startup: at Google, you're still being paid a relatively fat salary if your high-risk project fails, you just don't advance. And if it succeeds, you end up with a raise and a promotion, not F-U money [usually]. But this article is about the emotional aspects of failure, not the financial ones, and those are still just as relevant at fast-growers as at startups.)