I don't think Ruby's libraries honestly provide a whole lot better coverage than Go. The stdlib is very well considered. It's fast, it scales, it's thread safe in the appropriate places. It's not a toy implementation. What it doesn't provide, it provides hooks for. Third party libs cover all the major bases. And unlike Ruby, writing interfacing code in Go is a snip. I don't see libraries as a downside.
(With one exception. Why oh why did they not include a bigdecimal? Argh, a ratio type is not an adequate replacement. Try rounding a ratio some time. Blarg.)
Also realistically 60-70% of all libraries created for other languages are bitrotted to junk or pointlessness by this point.
If you can't see why an app that fits within the worked problemspace of Go (and even with the current libraries plenty of things are wholly doable in Go) and will require much less server resources might be a good fit, then you shouldn't be making those decisions, because that is the thought pattern of a zealot.
Look Ruby is well supported, established, and proven, but it is also slow. For a lot of things that is fine, but if you are dealing with something that requires a lot of serverside work on low margins it will kill you dead. Horses for courses.
P.S. Lots of people including me write lots of real world applications in Go...
It's a "cute" platform that I am sure will beat Ruby in a few benchmarks. But I don't see any reason why anyone would seriously consider it for a real world app.