Free floating has nothing to do with whether or not I can buy Rupees on the open market. If I choose to buy a ton, it could cause problems with their central bank who will have to produce supply in order to maintain the exchange peg.
My point is simply that it's pretty easy buy international currencies on the forex. IMHO easier than buying bit coins.
http://en.wikipedia.org/wiki/List_of_countries_with_floating...
In that respect BTC is similar to the USD/Euro/etc.
Also, Indian citizens are pretty heavily restricted from selling large amounts of rupees for dollars, etc. You need a lot of permissions and clearances for large amounts. (>$1M equivalent, earlier the limit used to be $1000!!)