I think these effects cancel out Haskell's relative lack of popularity unless you expect to be hiring at the enterprise Java level--something like literally thousands of developers.
Anyhow, keeping an open mind is the most important thing, and you clearly have no problems there. I just wish others would follow suit in that regard.
You might also consider a Haskell core, surrounded by a Python website. (Or any other website language/framework you like.) It strikes me as likely you have some sort of relatively small interface you can define between those two things, and then you can use the strengths of everything.
That said, It's a better choice than Scala for math. However, if the math is numerical algorithms, Python is better than either Haskell or Scala.
I'm not sure why they need to settle on one language. Seems like painting the bike shed. For better or worse, every sufficiently large web system has a number of languages being used behind the scenes.
I certainly do not think that syntax is anywhere near why some people find Haskell hard to pick up. Thanks to pattern matching, the syntax is very visual and thanks to having relatively few forms and keywords, it's much simpler than most imperative languages'.
Also, I'm not suggesting necessarily using Haskell exclusively, by any means; I just want more people to consider it at all!
However, its advantages are really not the important part. Rather, I just wish you wouldn't dismiss it immediately as a crazy choice. It's no more crazy than any other less-popular language. It has a reputation for being impractical, but this reputation is rather unfair especially in the light of recent very practical developments like simpler concurrency, an improved IO manager, very good web frameworks and a fair about of strong libraries both for very specific domains and general productivity.
The main disadvantage is that many people find it hard to learn. However, this is a function (heh) of functional programming rather than the language itself. It's actually a simpler language than Scala in many ways because it tries to do one thing well--for example, it has no sub-typing, so you do not have to ever worry about covariance and contravariance.
Now, my point here is not that you should always use Haskell, just that you should seriously consider it. Too many people dismiss it out of hand almost as a joke when it is anything but.