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Re:Ask HN: How do I tell OS X to use Spotify as standard mus... by pdenya on Monday February 11, 2013 @02:34PM (#5202760)
Alfred can global hotkey system commands. You could try binding that key to `open /Applications/Spotify.app` or something similar.

http://support.alfredapp.com/tutorials:global-hotkeys

This probably isn't the best forum for a question like this though, try http://superuser.com/ if Alfred doesn't work for you.

Re:Ask HN: How do I tell OS X to use Spotify as standard mus... by logn on Tuesday February 12, 2013 @05:24PM (#5210011)
Add to that RemoteBuddy if you have an apple remote:

http://www.iospirit.com/products/remotebuddy/

Re:Ask HN: How do I tell OS X to use Spotify as standard mus... by tblancpain on Monday February 11, 2013 @07:17PM (#5204360)
Thank you!