That chart is ordered by release; you start reading it at "3 o'clock" on the right hand side, and work clockwise.
Luckily they've labled each chunk of the pie. Normally they'd just have a key alongside it. People would have to match a shade of green (or some other color) to a key to try to get the numbers.
Pie charts do have uses. But they're just hard to read and present information in a weird way.
(http://pol.illinoisstate.edu/jpda/charts/chart%20tips/Charts...)
(http://www.juiceanalytics.com/writing/the-problem-with-pie-c...)
It's very hard to judge the relative size of various wedges, especially when they're not adjacent and one is significantly larger than the other.
Secondly, the labels are usually sufficiently removed from the data that you need to look back and forth several times to decode it, if you can even be bothered.
Here's a nearly useless pie chart: http://insights.chitika.com/uploads/screenshot-1.png
Here's a much more meaningful chart that tells a story: http://static.arstechnica.net/2012/04/02/firefox-adoption-20...