Mercurial for anything smaller or startup. Love it. The issue with Mercurial is that you'll need to determine how you want to do automated deploy builds, but the code management is great and using BitBucket + Hg I never have trouble seeing which code I'm working in or resolving conflicts. I actually think Mercurial has the second-best visual branching display.
Real big enterprise cannot use TFS without being in a mess with merge. You always have to merge to a parent which require a lot of organisation. Also, it's not the fastest source control when the code base is over few gigs per branches. With over 50 developers/testers (in the same project) we had reach a bottleneck with TFS.
Sourcesafe?
This is a BS argument.
Yes, everybody got it wrong, Git is wrong, SVN is wrong, it's CCs broken model that's correct.
" you need an army of administrators to make it work"
Yes, let's sink an awful amount of money in a half-baked software that needs all kinds of 'helpers' to work properly.
Personally I won't work in a company that uses CC anymore, and it's been only bliss since then.
Sourcesafe is bad, but it's a different kind of bad. And it makes even CC look good.