There are far more technologies going for the hours scale storage market than will survive. Sure, explore them. But expect most to fail to compete.
Grid level batteries have another very important metric. The actual possibility of buying a particular types of batteries from friendly nations. Simpler technologies like this CO2 battery have a huge advantage here.
To steelman the point you're making: perhaps the short term storage niche will fracture into smaller niches, in which different technologies could coexist. This also happens in ecology. For example, in one simple experiment with bacteria, it was found two species coexisted, but on closer examination it was found one species persisted in the top of the flasks, the other in the bottom.
For example, for the market niche "getting people from one location to another" there are quite many technologies, like walking, bicycles, scooters, cars, trains, ships, airplanes, helicopters etc., none of them evolved as a clear winner that displaced the others.
You might say, that's a whole market, not just a market niche, but it's also a niche of the larger transportation market.
When we look at something like grid-scale energy storage, how do we know if it's a winner-takes-all niche? Maybe constraints such as availability of space, availability of funding, weather, climate, grid demands etc. create sub-niches with their own winners. Or maybe not, but how can we known?