There's 4 to 6 hours of peak renewable energy per day.
If you add more batteries, you increase power and energy at the same time and ratio: so for any practical home battery system you're cycling the cells daily, which means you your power for charging must match.
If you put more batteries on one inverter, then you're scaling a lot of other costs (BMS, bus bars and space) but you'll never actually be able to utilize that capacity - it'll sit idle most of the time because you can't get it in and out of the cells fast enough.
I could go higher with a better inverter, but energy providers in Australia, or at least my part of it, basically drop all pretence once you go over 10kW feed-in, and the already pitiful rates they'll offer as standard asymptote towards zero.
Time of usage tariffs vary quite wildly here, but it's not uncommon to have close to 70c at peak hours, and 20c at off-peak. These fees are complicated by the daily connection charge, which is around $1.00 but varies on your location, provider, and your ToU and other schemes.
Some 'pretend to be a wholesaler' options exist here, but our wholesale pricing is bid and sold in 10m blocks, not 15m, as per your other note.
Also, we have ~6 hours a day where peak pricing is generally applied, and maybe ~9 hours where we're at off-peak pricing - so the math tends to be more compelling.
If you have 100kwh of batteries and only 6kw of AC connection then it would take 3 days of typical solar charging to get them to full capacity. And any kwh sitting there that you don't charge/discharge is costing you money for grid batteries - the economics still depend on being grid interactive.
The best demand signal in my local grid for example is exactly 1 hour wide. Which means s you get 4 15 minute intervals to basically try and dump power for the best price.