Why are you considering raid5/6? Are you considering building a large storage array? If the data will fit comfortably (50-60% utilization) on one drive, all you need is raid1. Btrfs is fine for raid1 (raid1c3 for extra redundancy); it might have hidden bugs, but no filesystem is immune from those; zfs had a data loss bug (it was rare, but it happened) a year ago.

Why use zfs for a boot partition? Unless you're using every disk mounting point and nvme slot for a single large raid array, you can use a cheap 512GB nvme drive or old spare 2.5" ssd for the boot volume. Or two, in btrfs raid1 if you absolutely must... but do you even need redundancy or datasum (which can hurt performance) to protect OS files? Do you really care if static package files get corrupted? Those are easily reinstalled, and modern quality brand SSDs are quite reliable.