With a guns you might need one or more well placed shots, and if you're not trained and proficient, that will be almost impossible if you find yourself in a situation where a bear is charging at you. Pepper spray can be a lot easier to spray in a bear's face in such a situation.
Might be best to have both spray and a gun handy, though.
https://www.bearwise.org/wp-content/uploads/2017/07/efficacy...
With a guns you might need one or more well placed shots, and if you're not trained and proficient, that will be almost impossible if you find yourself in a situation where a bear is charging at you. Pepper spray can be a lot easier to spray in a bear's face in such a situation.
Might be best to have both spray and a gun handy, though.