One in the very beginning of the show, when Walter’s old friend Elliott offers him a job at his company (that Walter originally created with him, but later quit, and then it ended up turning into a very successful business afterwards). With the explicit mention of their health insurance being able to cover all the costs of his treatment.
Then later in the show, Elliott and his wife straight up offered him money to cover everything, feeling that Walter deserves it (not in the least part, for being an original cofounder who was unlucky and quit right before the company got big).
There were more moments like those that i keep forgetting, but claiming that Walter started manufacturing drugs as some last resort to cover his medical bills is complete revisionism.
At the risk of going off topic, this is a popular, but incorrect meme. Walter could have had enough money for his cancer treatment, especially after getting the offer of paying it off by his former cofounders. He started selling drugs to provide for his family because his cancer was terminal. (And continued because of his own hubris.)