I develop and maintain multiple applications that use a worker pool, and are small enough to run on a single host. We used pg for the user sessions, which get read and written on every single page request. Some of our apps are Internet-facing, and web crawlers can create sessions that get read and written (recording recent pages) as they browse the site. We switched to a redis service on the same host as the app and saw 3 main benefits: faster session loading and saving, less disk activity on the Pg server (so all other queries run faster) and less writes to the Pg WAL, so our backups require drastically less GB per day of retention.

After the significant success of the first conversion, we've been working to convert all the rest of our apps.

And no, host language data structures aren't useful because they aren't in shared memory between all the worker processes, and even if we found a module that implemented them in shared memory, we like to be able to preserve the sessions across a host restart, and then we'd need a process to save the data structures to disk and load them back, and by the time we did that we'd have just reinvented redis.