Not generally, remember Ohm's Law I = V/R. Internally the body has a resistance of ~300 Ohms as a rough rule while our skin is 1000-10000 depending on the condition and contact area involved.

So 3V isn't going to pose any real risk unless it's applied internally and right across a critical nerve leading to your heart or a muscle directly on the heart. For reference pacemakers are generally set to 2-3 volts. Applied externally up to ~12V is generally considered low enough voltage there's a low risk of truly adverse effects.