Coreboot and some other low-level stuff uses cache-as-RAM during early steps of the boot process.

There was briefly a product called vCage loading a whole secure hypervisor into cache-as-RAM, with a goal of being secure against DRAM-remanence ("cold-boot") attacks where the DIMMs are fast-chilled to slow charge leakage and removed from the target system to dump their contents. Since the whole secure perimeter was on-die in the CPU, it could use memory encryption to treat the DRAM as untrusted.

So, yeah, you can do it. It's funky.