Non-signatories are overwhelmingly represented by a handful of countries with very large populations. None of the 5 most populated countries in the world are signatories, and out of the 10 most populated, only 4 are signatories (Nigeria, Brazil, Bangladesh, and Mexico). Out of the top 20 most populated countries, 10 are signatories.
Indonesia, Pakistan and Turkey have all previously expressed intentions of signing the Rome Statute, if only these countries would do so, it would bring over 60% of the world’s population under it.
The standard semantics of ‘most countries’ counts countries, not the people in them. Of course the related claim that the majority of /people/ do not live in state parties to the Rome Statute has different truth conditions.