They keep a pool of cash on hand to deal with this, but that pool was not big enough to absorb the GME mania. Robinhood eventually borrowed enough money to solve their liquidity problem, but by the time they did, the bubble popped, and the bagholders started screaming about fraud and collusion.
Banks are dragging their feet on customer-initiated transfers because of the fraud problem. If you send money by FedNow, it's gone. So there's a lot of scam potential. Wells Fargo supports bill pay via FedNow to known payees, which is useful. Pay a bill, and the payee gets paid immediately. Both sides can see the transaction as completed. That's useful.
The ability to send your entire bank account to anybody in seconds with no way to reverse the transaction is rather risky.
Robinhood needs FedNow support. That settles within 10 seconds. Then people can lose money faster.