If anyone expends as much effort at delivery (7 days, usually, with spaced repetition) of anything these days, I'd be seriously impressed.
> Implementing "quiet hours as seen in IM", means using the wrong tool.
Modern MUAs can usually do this sort of thing, tbf.
AFAICT using the MTA is a great way to avoid "can't stop looking syndrome"... I can't see the content of e-mails if all I see is 'rejected email from [email protected]' in the logs. Ofc, you need to reject them before they enter the queue -- that's the point!
Anyway, I don't particularly begrudge anybody solving problems in a way that works for them.
I mean, I do battle with notification-FOMO as much as anyone; if it works, go for it. I would just be tempted to poke at the rejected queue.
If you insist on treating e-mail as a medium requiring immediate response, you'll be going into Postfix on weekends to force-flush the queue instead. This is not a technological problem, definitely not one that's solvable through configuration tweaking.
(I mean, sure, it's an impressive exercise in how flexible the sw stack is, but the issue lies elsewhere)