In general, the idea (thermochemical hydrogen production) is just what you say -- heat in (solar, nuclear also researched), hydrogen out. No byproducts, as the chemical intermediates form a closed cycle.
[1] http://www.osti.gov/energycitations/product.biblio.jsp?osti_...
[2] http://en.wikipedia.org/wiki/Water_splitting
[3] http://www.udel.edu/udaily/2012/apr/solar-reactor-040312.htm...
The general idea is well known: http://en.wikipedia.org/wiki/Photocatalytic_water_splitting
This specific method is also well known: http://en.wikipedia.org/wiki/Zinc_zinc-oxide_cycle
And there are many other possible cycles: http://en.wikipedia.org/wiki/Water_splitting
At 2500c water will split into hydrogen without any help at all: http://en.wikipedia.org/wiki/High-temperature_electrolysis This reactor runs at 1600c.
This is basically a combination of the two things - use a lot of heat to make the reaction easier, and use solar catalyzed reactions to take it the rest of the way.