I've known quite a lot of CEOs, of small and big for-profits and charities too, and anecdotally they've all been some of the hardest working people I know. There's many complaints to make against many CEOs (including some of the ones I've known), often including taking obscene salaries while under-paying workers, or other problematic management decisions, but in my experience laziness just doesn't seem common - in exec levels generally as well as chief ones.
If you want to be lazy and paid well, there are easier jobs with less constant security than being a CEO!
If she's getting that salary she must be able to defend it as reasonable based on comparable salaries in the industry, the income she's able to secure for the company, etc. So if her pay seems like a lot, it's probably because the tech sector overall is paid too much in your opinion.
It’s niche.