Honestly, no more or less problems than Windows. But I've found it so much easier to debug by having readily available logs and man pages. I think this might just be my use cases though.
On any Linux DE, you have native configurable key shortcuts (binding commands to keystrokes).
On KDE, Win+right-click for resizing a window from anywhere in the window (no need to click the edges) is awesome. Win+left-click for moving a window from anywhere in the window (no need to click the title bar) is awesome. Ctrl+Alt+Esc to turn your cursor into a little skull and crossbones and instantly kill whatever program you click the window of is awesome. Dolphin is amazing compared to Explorer (tabs, split views, rich file metadata displayed right below filenames).
Windows UX has nothing on KDE's UX, and I never wanna go back to an OS that can't translate billions of dollars to features I can get for free because it treats me as a dataminable cost center.
Usability conventions between GUI applications. Keyboardability. GUI automation à la AutoHotKey. Font rendering. X vs. Wayland.