I worked for an ISP that was also a CLEC back in late 90s / early 2000s. All of the telco side was DC (massive 48v battery banks) - so when we were doing server implementation it made sense to get all DC PSU on the servers. Not sure why DC PSU aren't a more universal option as you'd think UPS providers could easily offer DC output models.
There are options out there, I ran across this [0] looking for typical ATX DC to DC PSU.
UPS systems start connecting the batteries in series to provide higher voltages for this reason
just ditch the 110 outlets for usb-a or usb-c ports and skip the inverter.
I'd love to power a pi or 3 from ups-based usb ports.
These cheaper ones just provide 9V and 12V output to power a fibre and/or WiFi router, as well as 5V USB-A, and start at around 30Wh capacity - some for less than USD 20. If you pay a little more, you can get 24/48V PoE included as well.
Unfortunately, ones providing USB-PD are quite rare. You do get "power stations" [2] with USB-PD (in addition to an AC inverter). These are typically USD 100 - USD 1000, and have much larger capacity.
Examples (I haven't tested these and do not specifically recommend them):
[1]: https://www.amazon.com/Lithium-Battery-Appliance-Monitor-uni...
[2]: https://www.amazon.com/Portable-Solar-Panel-Power-Station-Ge...
I really wish desktop PC power supplies would support such a thing. It seems stupid that we need to use a UPS with an inverter when the power supply should be rigged to accept DC input straight from a battery.