Yep, as we see it they compliment each other quite well. DevPod takes your workspace to the cloud and DevSpace let's you develop against your Kubernetes cluster - potentially the same one you used to start your workspace.

Internally we use both in our development setup, spinning up remote workspaces using DevPod, installing DevSpace and kind into the devcontainer, then using DevSpace to develop against the cluster. See the vcluster setup[1] as an example

[1]https://github.com/loft-sh/vcluster/tree/main/.devcontainer