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Re:Ask HN: Advice for learning Python as your first language? by TheDoctorWho on Sunday February 05, 2012 @02:10PM (#3554861)
http://learnpythonthehardway.org/

That is the best way to learn Python for a beginner, well at least in IMO

Re:Ask HN: Advice for learning Python as your first language? by vineetdhanawat on Sunday February 05, 2012 @02:57PM (#3555028)
Well, "A Byte of Python" is good to start resource!

http://www.swaroopch.com/notes/Python