It's even more insidious than that -- it is not only your fingertips that smell, since it penetrates the skin so readily. Pure DMSO itself is odorless, but it is metabolized into DMS, which stinks unbelievably strongly of garlic. The DMS has a very high systematic half-life (38 hours!!!) and remains dissolved in the blood, meaning your blood itself will stink of garlic for days after exposure.
The gut punch, however, is that the victim is reportedly unable to smell it (probably because their olfactory tissue is literally awash in DMS), so they don't realize they smell like walking garlic bread.
I've thought about trying it but have visions of it leaching the dye from my clothing and transporting it into my bloodstream. the garlic wouldn't make me many friends, but dissolving poisons is scarier.
Oh yeah, for the observer gallery: The reason DMSO (and DMF, DMAc, HF, to an extent haloforms, and polar aprotic solvents in general) are dangerous is that they can dissolve and transport small molecules (under 1000 daltons, possibly more) through your skin and into the bloodstream. They go straight through nitrile, vinyl, and latex gloves. You need to match the glove to the solvent. For these strong solvents, you want aliphatic polymers (LDPE) or laminates (mylar aka aluminized polyester).
Actually one of the best protection schemes is the shoulder-length polyethylene gloves used for ...ahem... bovine obstetrics, with nitrile over that for grip and to keep the cow glove in place. Looks hilarious but great for pouring nasty solutions or weighing dusty powders.
https://www.amazon.com/livestocktool-com-Disposable-Artifici...