If you are interested in SaaS, look at Elastic Path.
I see a lot of people recommending the MACH Alliance. That is a marketing organization where members pay in to push their products. Nothing wrong with MACH technology, but worth understanding what it is before going down that road.
[1] https://www.machalliance.com/members
[2] https://dev.to/voucherify/whats-mach-and-how-it-can-make-you...
However, the point the platforms are trying to make is that their APIs have been written with the explicit purpose of building a frontend ontop of them later on.
A lot of the old-school platforms have some APIs as well, but they are meant to e.g. import products or export orders. They are not meant to implement a frontend on top of, because they have a frontend engine as part of their monolith, and many functions you need to write a proper frontend will not be available through their APIs.
So the term "headless" means "we have APIs, and they are designed for you to build a frontend on top of".
https://www.howtogeek.com/660841/what-is-a-headless-server/
A “headless” computer system is just one without a local interface. There’s no monitor (“head”) plugged into it. There’s also no keyboard, mouse, touchscreen, or other local interface for controlling it.
Headless = frontend and backend are fully separated; the "promise" was to have the backend be used on multiple projects. You would have a headless backend, then a web frontend project, an iOS one, an Android one, etc without having to rewrite any backend code.
Of proprietary solutions Commercetools & Fabric are often mentioned among larger commerce businesses.